It is important to know the standard views and which arteries are best visualized in each. Wikipedia has a great article detailing this. It can be found here.
Summary:
LAO Views
RAO 20 Caud 20 - entire circ system plus first few cm of the LAD
PA 0 Caud 30 - LM bifurcation and Circumflex
LAO 50 Caud 30 - LMCA bifurcation
LAO 50 Cran 30 - Left Main (foreshortened), LAD, and its Diagonal Branches. Circ/Marg foreshortened and overlapped.
PA 0 Cran 40 - LAD and Diagonal bifurcation
RAO Views
LAO - Ostium is engaged in this view. Good for ostial and proximal RCA disease.
RAO 30 - MidRCA
PA 0 Cran 30 view with a small breath in - bifurcation of the distal RCA and rPDA